One of the three Caravelles used at this time by French Air Force in Polynesia. This one named "Teva" has been withdrawn from French Air Force inventory in 1996. Became later EL-EWY with Transair Congo, 3D-AUG for Waltair. Wfu in Kinshasa (Congo) in 2003.
Unfortunately the San Diego Air & Space Museum has little information with the photos in its collections. The vehicles makes it clear that this one was taken in Italy, and the Boeing 727 with '727' on the tail is a real smoking (pun intended) gun. It is demonstrator N7003U and oddly an old Portuguese newspaper report reveals that it visited Fiumicino circa 1 October 1963. Photo from: San Diego Air & Space Museum